There isn’t a big difference in performance between the 9900K and 9900KS.
Even running at 5.0 GHz, 5.1 GHz, 5.2 GHz, or 5.3 GHz on all cores, the performance difference isn’t significant. At most, you’re looking at around 5–10 FPS on average, and that’s only if you can keep the temperatures under control with air cooling.
With a closed-loop liquid cooler (AIO), the thermal situation may improve, allowing you to push the CPU further. However, you still won’t gain more than around 12–14 FPS at most.